Al-Qadisiyah Journal for Engineering Sciences

Corrosion inhibition performance of 2- Fluorophenyl-2, 5-dithiohydrazodicarbonamide for copper in 3.5%NaCl Media: Experimental and Monte Carlo insights

Document Type : Research Paper

Authors

Mothana Ghazi Kadhim AlFalah 1
Murat Saracoglu 2
Mehmet Izzettin Yilmazer 3
Fatma Kandemirli 4

1 Kastamonu University, Faculty of Engineering and Architecture, Metallurgy and Materials Engineering Department, 37150, Kastamonu, Türkiye

2 Erciyes University, Faculty of Education, 38039, Kayseri, Türkiye

3 Erciyes University, Faculty of Science, Department of Chemistry, 38039, Kayseri, Türkiye

4 Kastamonu University, Faculty of Engineering and Architecture, Biomedical Engineering Department, 37150, Kastamonu, Türkiye

https://doi.org/10.30772/qjes.2023.178995
Abstract
Most industries struggle with corrosion. Corrosion inhibitors are needed in these sectors. Eco-friendly corrosion inhibitors should be effective even at low concentrations. In this work, the compound 2- Fluorophenyl-2, 5- dithiohydrazodicarbonamide (2F-TSC) was utilized as a corrosion inhibitor for copper in a 3.5% NaCl solution. The inhibitor efficiency was calculated by using a series of electrochemical methods like, open circuit potential (OCP), potentiodynamic polarization (PDP), and electrochemical impedance spectroscopy (EIS). All tests have been done in a stagnant condition. The results show that the compound 2F-TSC looked to be of mixed type. Furthermore, the maximum inhibitor efficiency was reached at 99.2% at 10-2 M 2F-TSC and 5 h. The adsorption of 2F-TSC on the copper surface in 3.5% NaCl obeyed the Langmuir isotherm with a negative value of the standard Gibbs free energy of adsorption of -35.4 kJ/mol (chemisorption and physisorption). SEM, EDX, and AFM confirmed the presence of 2F-TSC on the surface of copper. The adsorption of the inhibitor molecules on the Cu (111) surface was further verified by a Monte Carlo simulation study. The results approved that the 2F-TSC can be utilized as a corrosion inhibitor for copper in an aggressive solution (3.5% NaCl).

Keywords

Copper
Corrosion resistance
EIS
Langmuir
Monte Carlo simulation
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Al-Qadisiyah Journal for Engineering Sciences
Volume 16, Issue 3
Summer 2023
Pages 150-159

  • Receive Date 03 March 2023
  • Revise Date 15 April 2023
  • Accept Date 25 July 2023

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