Document Type : Research Paper
Authors
1 Department of Environmental Engineering, College of Engineering, Mustansiriyah University, Baghdad, Iraq
2 Department of Petroleum Engineering, Faculty of Chemical Engineering, Tarbiat Modares University, Tehran, Iran
3 Department of Material Engineering, College of Engineering, University of Mustansiriyah, Baghdad, Iraq
10.30772/qjes.2024.145441.1069
Abstract
Adsorption behavior can be determined using different essential studies such as adsorption isotherm, kinetics, and thermodynamics. In this study, adsorption isotherm models, and kinetic, and thermodynamics studies are used to describe the use of alumina as an effective adsorbent and a remover of vanadium (V+5) ions from aqueous solutions contaminated by this metal. The aqueous solutions used simulate the wastewater of most traditional oil refineries. Efficiency can be determined by comparing the correlation coefficients of the linear relationships used with each model. Using alumina, the perfect removal of vanadium ions was achieved. Vanadium removal increases with an increase in the operating conditions, which are time temperature, agitation speed, pH, and adsorbent’s media dose. However, it also increases with the elimination of the initial concentration. This study shows that the vanadium’s adsorption based on the Langmuir isotherm model gives a correlation coefficient of 0.9999, while when it is based on the Temkin and Freundlich isotherms the correlation coefficient is less. Hence, adsorption on the surface of alumina takes place in monolayer surfaces with a regular distribution of particle’s binding energy and a narrow quantity of identical sites on the surface of alumina. Subsequently, the kinetic study shows that the adsorption behavior matched the pseudo-second-order kinetic model with R2 equaling 0.9999. Also, thermodynamics studies approves that the adsorption is a spontaneous endothermic process of enthalpy change.
Keywords
- Abbas, M. N., & Alalwan, H. A., (2019). Catalytic Oxidative and Adsorptive Desulfurization of Heavy Naphtha Fraction. Korean Journal of Chemical Engineering, 12(2), 283-288. http://doi.org/10.9713/kcer.2019.57.2.283
- Abbas, M. N., & Ibrahim, S. A., (2020). Catalytic and thermal desulfurization of light naphtha fraction. Journal of King Saud University - Engineering Sciences, 32(4), 229-235. https://doi.org/10.1016/j.jksues.2019.08.001
- Ali, G. A. A., Ibrahim, S. A., & Abbas, M. N., (2021). Catalytic Adsorptive of Nickel Metal from Iraqi Crude Oil using non-Conventional Catalysts. Innovative Infrastructure Solutions, 6, Article No. 7, 9 pages. https://doi.org/10.1007/s41062-020-00368-x
- Alhamd, S. J., Abbas, M. N., Manteghian, M., Ibrahim, T. A., & Jarmondi, K. D. S., (2024). Treatment of Oil Refinery Wastewater Polluted by Heavy Metal Ions via Adsorption Technique using Non-Valuable Media: Cadmium Ions and Buckthorn Leaves as a Study Case. Karbala International Journal of Modern Science. https://doi.org/10.33640/2405-609X.3334
- Shadhan, Z. J., & Abbas, M. N., (2021). Removal of Heavy Metals from Refineries Wastewater. Journal of Engineering and Sustainable Development, 2nd online Scientific conference for Graduate Engineering Students, June. https://doi.org/10.31272/jeasd.conf.2.3.9
- Abbas, M. N., & Abbas, F. S., (2013). Iraqi Rice Husk Potency to Eliminate Toxic Metals from Aqueous Solutions and Utilization from Process Residues. Advances in Environmental Biology, 7(2), 308-319
- Taha F. M., Mohammad A. K., & Sabeeh N. S., (2021). Treatment of oily wastewater by using polysulfide polymer. Al-Qadisiyah Journal for Engineering Sciences, 14(3), 144-150, September. https://doi.org/10.30772/qjes.v14i3.777
- Hawass Z. A., & AlJaberi F. Y., (2022). Effect of mono and bipolar connection modes on the electrocoagulation removal efficiency of multi-heavy metals from simulated wastewater. Al-Qadisiyah Journal for Engineering Sciences, 15(1), 48-54, March. https://doi.org/10.30772/qjes.v15i1.813
- Abbas, M. N., Ali, S. T., & Abbas, R. S., (2020). Rice Husks as a Biosorbent Agent for Pb+2 Ions from Contaminated Aqueous Solutions: A Review. Biochemical and Cellular Archives, 20(1), 1813-1820. https://doi.org/10.35124/bca.2020.20.1.1813
- Abbas, M. N., & Abbas, F. S., (2013). The Predisposition of Iraqi Rice Husk to Remove Heavy Metals from Aqueous Solutions and Capitalized from Waste Residue. Research Journal of Applied Sciences, Engineering and Technology, 6(22), 4237-4246
- Abdulkareem, W. S., Aljumaily, H. S. M., Mushatat, H. A., & Abbas M. N., (2023). Management of Agro-Waste by Using as an Additive to Concrete and Its Role in Reducing Cost Production: Impact of Compressive Strength as a Case Study. International Journal on “Technical and Physical Problems of Engineering” (IJTPE), 15(54), 62-67
- Maddodi, S. A., Alalwan, H. A., Alminshid, A. H., & Abbas, M. N., (2020). Isotherm and computational fluid dynamics analysis of nickel ion adsorption from aqueous solution using activated carbon. South African Journal of Chemical Engineering, 32, 5-12. https://doi.org/10.1016/j.sajce.2020.01.002
- Abbas, M. N., & Abbas, F. S., (2014). Application of Rice Husk to Remove Humic Acid from Aqueous Solutions and Profiting from Waste Leftover. WSEAS Transactions on Biology and Biomedicine, 11, 62-69
- Abbas, M. N., & Abbas, F. S., (2013). The Feasibility of Rice Husk to Remove Minerals from Water by Adsorption and Avail from Wastes. Research Journal of Applied Sciences, WSEAS Transactions on Environment and Development, 9(4), 301-313
- Abdullah, W. R., Alhamadani, Y. A. J., Abass, I. K., & Abbas, M. N., (2023). Study of chemical and physical parameters affected on purification of water from inorganic contaminants. Periodicals of Engineering and Natural Sciences, 11(2), 166-175. http://dx.doi.org/10.21533/pen.v11i2.3508
- Abbas, M. N., & Nussrat, T. H., (2020). Statistical Analysis of Experimental Data for Adsorption Process of Cadmium by Watermelon Rinds in Continuous Packed Bed Column. International Journal of Innovation, Creativity and Change, 13(3), 124-138
- Ali, S. A. K., Almhana, M., Hussein, A. A., & Abbas, M. N., (2020). Purification of Aqueous Solutions from Toxic Metals using Laboratory Batch Mode Adsorption Unit Antimony (V) Ions as a Case Study. Journal of Green Engineering (JGE), 10(11),10662-10680
- Al-Ali, S. I. S., Ibrahim, S. A., Abbas, M. N., & Ibrahim, T. A., (2024). Mathematical Modelling of Selenium Adsorption using Pomegranate Peel. Tikrit Journal of Engineering Sciences, under publishing
- Hasan, M. B., Al-Tameemi, I. M., & Abbas, M. N., (2021). Orange Peels as a Sustainable Material for Treating Water Polluted with Antimony. Journal of Ecological Engineering, 22(2), 25-35. https://doi.org/10.12911/22998993/130632
- Al-Hermizy, S. M. M., Al-Ali, S. I. S., Abdulwahab, I. A., & Abbas M. N., (2022). Elimination of Zinc Ions (Zn+2) from Synthetic Wastewater Using Lemon Peels. Asian Journal of Water, Environment and Pollution, 19(5), 79-85. https://doi.org/10.3233/AJW220073
- Al-Ali, S. I. S., Abudi, Z. N., & Abbas, M. N., (2023). Modelling and Simulation for the use of Natural Waste to Purified Contaminated Heavy Metals. Journal of the Nigerian Society of Physical Sciences, 5(1), Article No. 1143. https://doi.org/10.46481/jnsps.2023.1143
- Abbas, M. N., Al-Hermizy, S. M. M., Abudi, Z. N., & Ibrahim, T. A., (2019). Phenol Biosorption from Polluted Aqueous Solutions by Ulva lactuca Alga using Batch Mode Unit. Journal of Ecological Engineering, 20(6), 225–235. https://doi.org/10.12911/22998993/109460
- Hashem, N. S., Ali, G. A. A., Jameel, H. T., Khurshid, A. N., & Abbas, M. N., (2021). Heavy Metals Evaluation by Atomic Spectroscopy, for Different Parts of Water Hyacinth (Eichhornia crassipes) Plants Banks of Tigris River. Biochemical and Cellular Archives, 21(2), 3813-3819. https://connectjournals.com/03896.2021.21.3813
- Ghanim A. N., (2023). Utilization of date pits derived Bio-adsorbent for heavy metals in wastewater treatment: Review. Al-Qadisiyah Journal for Engineering Sciences, 16(1), 58-69, March. https://doi.org/10.30772/qjes.v16i1.910
- Ibrahim, S. A., Hasan, M. B., Al-Tameemi, I. M., Ibrahim, T. A., Abbas, M. N., (2021). Optimization of adsorption unit parameter of hardness remediation from wastewater using low-cost media. Innovative Infrastructure Solutions, 6(4), Article No: 200. https://doi.org/10.1007/s41062-021-00564-3
- Alalwan, H. A., Abbas, M. N., & Alminshid, A. H., (2020). Uptake of Cyanide Compounds from Aqueous Solutions by Lemon Peel with Utilising the Residue Absorbents as Rodenticide. Indian Chemical Engineer, 62(1), 40-51. https://doi.org/10.1080/00194506.2019.1623091
- Alalwan, H. A., Mohammed, M. M., Sultan, A. J., Abbas, M. N., Ibrahim, T. A., Aljaafari, H. A. S., & Alminshid, A. A., (2021). Adsorption of methyl green stain from aqueous solutions using non-conventional adsorbent media: Isothermal kinetic and thermodynamic studies. Bioresource Technology Reports, 14, Article No.100680. https://doi.org/10.1016/j.biteb.2021.100680
- Ibrahim, T. A., Mohammed, A. M., Abd ali, I. K., Abbas, M. N., & Hussien S. A., (2020). Teratogenic Effect of Carbamazepine Drug on the Histological Structure of Testes in the Albino Mouse (Mus musculus). Indian Journal of Forensic Medicine & Toxicology, 14(4), 1829-1834. https://doi.org/10.37506/ijfmt.v14i4.11809
- Abd ali, I. K., Ibrahim, T. A., Farhan, A. D., & Abbas M. N., (2018). Study of the effect of pesticide 2,4-D on the histological structure of the lungs in the albino mice (Mus musculus). Journal of Pharmaceutical Sciences and Research, 10(6), 1418-1421
- Abd Al-Latif F. S., Ibrahim T. A., and Abbas M. N., (2023), “Revealing Potential Histological Changes of Deltamethrin Exposure on Testicular Tissue in Albino Rabbits (Oryctolagus cuniculus)”, Advancements in Life Sciences, Volume 10, Number 4, pp: 619-626
- Alalwan, H. A., Abbas, M. N., Abudi, Z. N., & Alminshid, A. H., (2018). Adsorption of thallium ion (Tl+3) from aqueous solutions by rice husk in a fixed-bed column: Experiment and prediction of breakthrough curves. Environmental Technology and Innovation, 12, 1-13. https://doi.org/10.1016/j.eti.2018.07.001
- Abbas, M. N., Al-Tameemi, I. M., Hasan, M. B., & Al-Madhhachi, A. T., (2021). Chemical Removal of Cobalt and Lithium in Contaminated Soils using Promoted White Eggshells with Different Catalysts. South African Journal of Chemical Engineering, 35, 23-32. https://doi.org/10.1016/j.sajce.2020.11.002
- Abbas, M. N., Al-Madhhachi, A. T., & Esmael, S. A., (2019). Quantifying soil erodibility parameters due to wastewater chemicals. International Journal of Hydrology Science and Technology, 9(5), 550-568. http://doi.org/10.1504/IJHST.2019.10016884
- Ali, G. A. A., & Abbas, M. N., (2020). Atomic Spectroscopy Technique Employed to Detect the Heavy Metals from Iraqi Waterbodies Using Natural Bio-Filter (Eichhornia crassipes) Thera Dejla as a Case Study. Systematic Reviews in Pharmacy, 11(9), 264-271. https://doi.org/10.31838/srp.2020.9.43
- Abbas, F. S., Abdulkareem, W. S., & Abbas, M. N., (2022). Strength Development of Plain Concrete Slabs by the Sustainability Potential of Lead-Loaded Rice Husk (LLRH). Journal of Applied Engineering Science, 20(1), 160-167. https://doi:10.5937/jaes0-32253
- Rajaa, N., Kadhim, F. J., Abbas, M. N., & Banyhussan, Q. S., (2023). The improvement of concrete strength through the addition of sustainable materials (agro-waste loaded with copper ions). 3rd International Conference for Civil Engineering Science (ICCES 2023), IOP Conf. Series: Earth and Environmental Science, 1232, Article No. 012038, 9 Pages. http://doi.org/10.1088/1755-1315/1232/1/012038
- Abbas, M. N., Ibrahim, S. A., Abbas, Z. N., & Ibrahim, T. A., (2022). Eggshells as a Sustainable Source for Acetone Production. Journal of King Saud University - Engineering Sciences, 34(6), 381-387. https://doi.org/10.1016/j.jksues.2021.01.005
- Abbas M. N., (2015). Phosphorus removal from wastewater using rice husk and subsequent utilization of the waste residue. Desalination and Water Treatment, 55(4), 970-977. https://doi.org/10.1080/19443994.2014.922494
- Ibrahim, T. A., Mahdi, H. S., Abbas, R. S., & Abbas, M. N., (2020). Study the Effect of Ribavirin Drug on the histological structure of the testes in Albino mice (Mus musculus). Journal of Global Pharma Technology, 12(02 Suppl.), 142-146
- Alminshid, A. H., Abbas, M. N., Alalwan, H. A., Sultan, A. J., & Kadhome, M. A., (2021). Aldol condensation reaction of acetone on MgO nanoparticles surface: An in-situ drift investigation. Molecular Catalysis, 501, Article No. 111333. https://doi.org/10.1016/j.mcat.2020.111333
- Alwan, E. K., Hammoudi, A. M., Abd, I. K., Abd Alaa, M. O., & Abbas, M. N., (2021). Synthesis of Cobalt Iron Oxide Doped by Chromium Using Sol-Gel Method and Application to Remove Malachite Green Dye. NeuroQuantology, 19(8), 32-41. http://doi:10.14704/nq.2021.19.8.NQ21110
- Khaleel, L. R., Al-Hermizy, S. M., & Abbas M. N. (2022). Statistical Indicators for Evaluating the Effect of Heavy Metals on Samaraa Drug Industry Water Exposed to the Sun and Freezing, Tropical Journal of Natural Product Research, 6(12), 1969-1974. http://www.doi.org/10.26538/tjnpr/v6i12.12
- Ali, S. A. K., AL-Kaabi Z., Kasim, M. N., Abbas, M. N., & Ibrahim, T. A., (2024). Remediation of Antimony from Aqueous Solutions by Adsorption Technique: Isothermal, Kinetic, and Thermodynamic Studies. Indian Journal of Environmental Protection. Under publishing
- Ghulam, N. A., Abbas, M. N., & Sachit, D. E., (2020). Preparation of synthetic alumina from aluminium foil waste and investigation of its performance in the removal of RG-19 dye from its aqueous solution. Indian Chemical Engineer, 62(3), 301-313. https://doi.org/10.1080/00194506.2019.1677512
- Ali, S. T., Qadir, H. T., Moufak, S. K., Al-Badri, M. A. M., & Abbas M. N., (2020). A Statistical Study to Determine the Factors of Vitamin D Deficiency in Men the City of Baghdad as a Model. Indian Journal of Forensic Medicine & Toxicology, 14(1), 691-696, January-March. https://doi.org/10.37506/ijfmt.v14i1.132
- Le Q. H., Smida K., Abdelmalek Z., & Tlili I., (2021). Removal of heavy metals by polymers from wastewater in the industry: A molecular dynamics approach. Engineering Analysis with Boundary Elements. 155, 1035-1042.
- Kassob A. N., & Abbar A. H., (2022). Treatment of petroleum refinery wastewater by adsorption using activated carbon fixed bed column with batch recirculation mode. Al-Qadisiyah Journal for Engineering Sciences, 15(2), 101-111, June. https://doi.org/10.30772/qjes.v15i2.820
- Abdulrahman, M. A., Al-Ali, S. I. S., and Abbas, M. N., (2024). Interface Shapes and Flow Behaviour in Duct Systems under Critical and Sub-Critical Flow Conditions. Al-Qadisiyah Journal for Engineering Sciences (QJES), in press. https://doi.org/10.30772/qjes.2023.143635.1037
- Adnan, M. S., Khalil, A. A., and Alhamd, S. J., (2023). The effect of varying shale concentrations on wellbore instability in drilling operations for Iraqi oil fields. AIP Conf. Proc. 2631(1). 070003. https://doi.org/10.1063/5.0140124
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