Document Type : Research Paper
Authors
1 Chemical Engineering Department, Faculty of Engineering, University of Al-Qadisiyah, Al-Diwaniya 58002, Iraq.
2 Chemical Engineering Department, Babol Noshirvani University of Technology, Babol, Iran.
3 Mechanical Engineering of Department, Trafford College Group, Manchester, United Kingdom.
Abstract
Biodiesel is a promising alternative to conventional fossil fuels, so effective catalysis is essential to enhance the efficiency and selectivity in biodiesel production. This article discusses one of the methods used to synthesize these catalysts and their effectiveness in biofuel production. A catalyst was synthesized from palm frond waste, which is abundant in Iraq. Palm frond dust acquired magnetic properties by adding iron (III) chloride by the impregnation method. Palm frond dust was carbonized for 3 h at 700 C°and then sulfonated using (H2SO4) depending on variable factors such as reaction time, temperature, and acid concentration. The change of these factors on the acidity value of the catalyst was studied. The catalyst was characterized using techniques such as FTIR, SEM, acid value, and BET. The study successfully prepared an effective magnetic catalyst with the possibility of recovery due to its magnetic properties. The surface area determined by BET was 585.12 m2/g, indicating a high specific surface area value. The highest expected acid value was 4.23 mmol/g at a reaction time of 2.6 h°, a temperature of 50 C°, and a concentration of 10 M.
Keywords
- Nazzal and A. Jazie, “Green diesel production using egg shell derived cao catalyst: Effect of catalyst and reaction process,” Al-Qadisiyah Journal for Engineering Sciences, vol. 13, no. 4, pp. 262–267, March 2020. [Online]. Available: http://doi.org/10.30772/qjes.v13i4.697
- M. Mezher and H. Mohammed Al.Tameemi, “A catalytic cracking process on atmospheric residue from the al-diwaneyah petroleum refinery,” Al-Qadisiyah Journal for Engineering Sciences, vol. 15, no. 3, pp. 164– 170, 2022. [Online]. Available: https://doi.org/10.30772/qjes.v15i3.829
- Ang, W. Choong, and T. Ng, “Energy security: Definitions, dimensions and indexes,” Renewable and Sustainable Energy Reviews, vol. 42, pp. 1077–1093, 2015. [Online]. Available: https://doi.org/10.1016/j.rser.2014.10.064
- -Z. Ang, M. Salem, M. Kamarol, H. Das, M. Nazari, and N. Prabaharan, “A comprehensive study of renewable energy sources: Classifications, challenges and suggestions,” Energy Strategy Reviews, vol. 43, p. 100939, 2022. [Online]. Available: https://doi.org/10.1016/j.esr.2022.100939
- Hassan, P. Viktor, T. J. Al-Musawi, B. M. Ali, S. Algburi, H. Alzoubi, A. K. Al-Jiboory, A. Z. Sameen, H. Salman, and M. Jaszczur, “The renewable energy role in the global energy transformations,” Renewable Energy Focus, vol. 48, p. 100545, 2024. [Online]. Available: https://doi.org/10.1016/j.ref.2024.100545
- Huang, H. Zhou, and L. Lin, “Biodiesel: an alternative to conventional fuel,” Energy Procedia, vol. 16, no. Part c, pp. 1874–1885, 2012. [Online]. Available: https://doi.org/10.1016/j.egypro.2012.01.287
- Changmai, C. Vanlalveni, A. Ingle, R. Bhagat, and S. Rokhum, “Widely used catalysts in biodiesel production: a review,” RSC Advances, vol. 10, pp. 41 625–41 679, 2020. [Online]. Available: https://doi.org/10.26434/chemrxiv.13095551.v2
- Singh, R. Saluja, H. Rao, R. Kaushal, N. Gahlot, I. Suyambulingam, M. Sanjay, D. Divakaran, and S. Siengchin, “Progress and facts on biodiesel generations, production methods, influencing factors, and reactors: A comprehensive review from 2000 to 2023,” Energy Conversion and Management, vol. 302, p. 118157, 2024. [Online]. Available: https://doi.org/10.1016/j.enconman.2024.118157
- Das and S. Rokhum, “Chapter 6 - renewable diesel and biodiesel: a comparative analysis, in: D. kumar, b. singh, s.k. gupta (eds.),” Renewable Diesel, pp. 123–166, 2024. [Online]. Available: https://doi.org/10.1016/B978-0-323-91153-5.00002-9
- Kamaraj, Y. Rao, and B. B, “Biodiesel blends: a comprehensive systematic review on various constraints,” Environmental Science and Pollution Research, vol. 29, no. 1, p. 43770–43785, 2021. [Online]. Available: https://doi.org/10.1007/s11356-021-13316-8
- Kalita, B. Basumatary, P. Saikia, B. Das, and S. Basumatary, “Biodiesel as renewable biofuel produced via enzyme-based catalyzed transesterification,” Energy Nexus, vol. 6, p. 100087, 2022. [Online]. Available: https://doi.org/10.1016/j.nexus.2022.100087
- Hussain, M. Haider, M. Tripathi, and R. Kumar, “Catalytic and non-catalytic methods for biodiesel production, in: K.k. pant, s.k. gupta, e. ahmad (eds.),” Catalysis for Clean Energy and Environmental Sustainability: Biomass, pp. 185–208, 2021. [Online]. Available: http://doi.org/10.1007/978-3-030-65017-9 7
- Schuchardt, R. Sercheli, and V. Matheus, “Transesterification of vegetable oils: A review,” Journal of the Brazilian Chemical Society, vol. 9, no. 3, 1998. [Online]. Available: http://doi.org/10.1590/S0103-50531998000300002
- Filippi and C. Pizzolitto, “The past and the future of catalysis and technology in industry: a perspective from casale sa point of view,” Catalysis Today, vol. 387, no. 1, pp. 9–11, 2022. [Online]. Available: https://doi.org/10.1016/j.cattod.2021.11.005
- Jayakumar, N. Karmegam, M. Gundupalli, K. B. Gebeyehu, B. T. Asfaw, S. Chang, B. Ravindran, and M. K. Awasthi, “Heterogeneous base catalysts: Synthesis and application for biodiesel production – a review,” Bioresource Technology, vol. 331, p. 125054, 2021. [Online]. Available: https://doi.org/10.1016/j.biortech.2021.125054
- Krishnan, F. l. Pua, and F. Zhang, “A review of magnetic solid catalyst development for sustainable biodiesel production,” Biomass and Bioenergy, vol. 149, no. 1, p. 106099, 2021. [Online]. Available: https://doi.org/10.1016/j.biombioe.2021.106099
- Maquirriain, C. Querini, and M. Pisarello, “Glycerine esterification with free fatty acids: Homogeneous catalysis,” Chemical Engineering Research and Design, vol. 171, pp. 86–99, 2021. [Online]. Available: https://doi.org/10.1016/j.cherd.2021.04.018
- Orege, O. Oderinde, G. Kifle, A. Ibikunle, S. Raheem, O. Ejeromedoghene, E. Okeke, O. Olukowi, O. Orege, E. Fagbohun, T. Ogundipe, E. Avor, O. Ajayi, and M. Daramola, “Recent advances in heterogeneous catalysis for green biodiesel production by transesterification,” Energy Conversion and Management, vol. 258, p. 115406, 2022. [Online]. Available: https://doi.org/10.1016/j.enconman.2022.115406
- Xie and J. Li, “Magnetic solid catalysts for sustainable and cleaner biodiesel production: A comprehensive review,” Renewable and Sustainable Energy Reviews, vol. 171, p. 113017, 2023. [Online]. Available: https://doi.org/10.1016/j.rser.2022.113017
- Akbarzadeh, M. Samiei, and S. Davaran, “Magnetic nanoparticles: preparation, physical properties, and applications in biomedicine,” Nanoscale Research Letters, vol. 7, no. 144, 2012. [Online]. Available: https://doi.org/10.1186/1556-276X-7-144
- Basumatary, S. Brahma, M. Hoque, B. Das, M. Selvaraj, S. Brahma, and S. Basumatary, “Advances in cao-based catalysts for sustainable biodiesel synthesis,” Green Energy and Resources, vol. 1, no. 3, p. 100032, 2023. [Online]. Available: https://doi.org/10.1016/j.gerr.2023.100032s
- Mabate, N. Maqunga, S. Ntshibongo, M. Maumela, and N. Bingwa, “Metal oxides and their roles in heterogeneous catalysis: special emphasis on synthesis protocols, intrinsic properties, and their influence in transfer hydrogenation reactions,” SN Applied Sciences, vol. 5, no. 196, 2023. [Online]. Available: https://doi.org/10.1007/s42452-023-05416-6
- V. Allsburg, E. Tan, J. Super, J. Schaidle, and F. Baddour, “Early-stage evaluation of catalyst manufacturing cost and environmental impact using catcost,” Nature Catalysis, vol. 5, pp. 342–353, 2022. [Online]. Available: https://doi.org/10.1038/s41929-022-00759-6
- Umakanth, A. Datta, B. Reddy, and S. Bardhan, “Chapter 3 - biomass feedstocks for advanced biofuels: Sustainability and supply chain management,” in: D. Tuli, S. Kasture, A. Kuila (Eds.)Advanced Biofuel Technologies, pp. 39–72, 2022. [Online]. Available: https://doi.org/10.1016/B978-0-323-88427-3.00023-4
- Chutia and K. Phukan, “Biomass derived heterogeneous catalysts used for sustainable biodiesel production: a systematic review,” Brazilian Journal of Chemical Engineering, vol. 41, pp. 23–48, 2024. [Online]. Available: http://doi.org/10.1007/s43153-023-00371-6
- Gonc,alves, H. Santos, M. da Silva, A. da Cas Viegas, G. da Rocha Filho, and L. da Conceic, ˜ao, “Biodiesel production from waste cooking oil using an innovative magnetic solid acid catalyst based on ni–fe ferrite: Rsm-bbd optimization approach,” Journal of Industrial and Engineering Chemistry, vol. 135, pp. 270–285, 2024. [Online]. Available: https://doi.org/10.1016/j.jiec.2024.01.038
- Khan, S. Khan, L. Khan, A. Farooq, K. Akhtar, and A. Asiri, “Fourier transform infrared spectroscopy: Fundamentals and application in functional groups and nanomaterials characterization,” Handbook of Materials Characterization, pp. 317–344, 2018. [Online]. Available: https://doi.org/10.1007/978-3-319-92955-2 9
- Liu, P. Lv, Z. Yuan, F. Yan, and W. Luo, “The nanometer magnetic solid base catalyst for production of biodiesel,” Renewable Energy, vol. 35, no. 7, pp. 1531–1536, 2010. [Online]. Available: https://doi.org/10.1016/j.renene.2009.10.009
- Brahmayya, S. Dai, and S.-Y. Suen, “Sulfonated reduced graphene oxide catalyzed cyclization of hydrazides and carbon dioxide to 1,3,4-oxadiazoles under sonication,” Scientific Reports, vol. 7, no. 4675, pp. 341–354, 2017. [Online]. Available: http://doi.org/10.1038/s41598-017-04143-4
- R. Pouran, A. A. Raman, and W. Daud, “Review on the application of modified iron oxides as heterogeneous catalysts in fenton reactions,” Journal of Cleaner Production, vol. 64, pp. 24–35, 2014. [Online]. Available: http://doi.org/10.1016/j.jclepro.2013.09.013(2013)
- Thommes, K. Kaneko, A. Neimark, J. Olivier, F. Rodriguez-Reinoso, J. Rouquerol, and K. Sing, “Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (iupac technical report),” Pure and Applied Chemistry, vol. 87, pp. 1051–1069, 2015. [Online]. Available: https://doi.org/10.1515/pac-2014-1117
- Gaffney and N. Marley, “Fourier transform infrared (ftir) spectroscopy,” Energy and Buildings, no. 1, p. 57, 2012. [Online]. Available: https://doi.org/10.1002/0471266965.com107.pub2
- Tian, Q. Shen, Z. Fu, Y. Wu, and C. Jia, “Enhanced adsorption desulfurization performance over hierarchically structured zeolite y,” Fuel Processing Technology, vol. 128, no. 6, pp. 176–182, 2014. [Online]. Available: https://doi.org/10.1016/j.fuproc.2014.07.018
- Amanzadeh, J. Ahmadpour, S. Shabanian, and M. Nikzad, “Experimental, isotherm, kinetic, and thermodynamic studies of the novel modified zeolite zsm-5 adsorbent for use in clean fuel processing,” Chemical Engineering Research and Design, vol. 203, no. 5, pp. 69–82, 2024. [Online]. Available: https://doi.org/10.1016/j.cherd.2024.01.032
- Miedaner, R. Weerasooriya, and H. Tobschall, “Chapter 17 - 1-pk modeling strategies for the adsorption of some trace elements onto gibbsite,” J. L¨utzenkirchen (Ed.) Interface Science and Technology, Elsevier, vol. 11, pp. 469–490, 2006. [Online]. Available: https://doi.org/10.1016/S1573-4285(06)80061-X
- Ehiomogue, I. Ahuchaogu, and I. Ahaneku, “Review of adsorption isotherms models,” ACTA TECHNICA CORVINIENSIS – Bulletin of Engineering Tome XIV, no. 8, p. 79–87, 2022.