Department of Metallurgical Engineering, Materials Engineering College, University of Babylon, Babylon, Iraq.
10.30772/qjes.2024.151081.1280
Abstract
The performance of functionally graded materials is much better than materials with unchanged properties and compositions. Al-Cr-Fe alloys with different Cr concentrations were proposed for this work. Potential applications for these materials include automotive pistons. FGM was fabricated by a successive stage of the sequential casting method with mechanical vibration during the solidification. The FGM sample consists of two alloys with different chemical compositions (Al-8Si-2Fe) and (Al-2Cr-2Fe). Two types of samples were studied and compared, with and without mold vibration. The method of mechanical mold vibration, which in turn reduces the segregation and pores in the cast and refines the microstructure. The results of the XRD showed the presence of α-Al phase, Al₈₀Cr₁₃.₅Fe₆.₅, Al₁₃Cr₂, and Al₁₃Fe₄ compounds that enhance the strength of the alloy. Optical microscope images showed a difference in the microstructure at both sides of the interface between the two alloys. There is variation in the hardness values due to the difference in the chemical composition of the alloys. The recorded improvement in the tensile strength was 17%, and a decrease in Compression by 1.5%.
Botero, C., Koptyug, A., Sjöström, W., Jiménez-Piqué, E., Şelte, A., & Rännar, L. E. Functionally Graded Steels Obtained via Electron Beam Powder Bed Fusion. Key Engineering Materials, 964, 79-84 (2023). https://doi.org/10.4028/p-xaC6qO
Młynarek-Żak, K., Pakieła, W., Łukowiec, D., Bajorek, A., Gębara, P., Szakál, A. & Babilas, R. Structure and selected properties of Al–Cr–Fe alloys with the presence of structurally complex alloy phases. Scientific Reports, 12, 14194 (2022).https://doi.org/10.1038/s41598-022-17870-0
Li, R., Yu, W., Zhang, Y., Li, C., Qu, Y., Nie, S., ... & Yu, B. Effect of phase proportion on wear behavior of Al–Cr–Fe–Ni dual-phase high entropy alloys. Metallography, Microstructure, and Analysis, 10, 106-115 (2021). https://doi.org/ 10.1007/s13632-020-00709-3
Yang, S., Lu, J., Xing, F., Zhang, L., & Zhong, Y. Revisit the VEC rule in high entropy alloys (HEAs) with high-throughput CALPHAD approach and its applications for material design-A case study with Al–Co–Cr–Fe–Ni system. Acta Materialia, 192, 11-19 (2020). https://doi.org/10.1016/j.actamat.2020.03.039
Ribeiro, T. M., Catellan, E., Garcia, A., & dos Santos, C. A. The effects of Cr addition on microstructure, hardness and tensile properties of as-cast Al–3.8 wt.% Cu–(Cr) alloys. Journal of Materials Research and Technology, 9(3), 6620-6631 (2020). https://doi.org/ 10.1016/j.jmrt.2020.04.054
Koller, C. M., Kirnbauer, A., Hahn, R., Widrig, B., Kolozsvári, S., Ramm, J., & Mayrhofer, P. H. Oxidation behavior of intermetallic Al-Cr and Al-Cr-Fe macroparticles. Journal of Vacuum Science & Technology A, 35(6) (2017). https://doi.org/10.2139/ssrn.4705444
de Araujo, A. P., Micheloti, L., Kiminami, C. S., & Gargarella, P. Microstructure, phase formation and properties of rapid solidified Al–Fe–Cr–Ti alloys. Materials Science and Technology, 36(11), 1205-1214 (2020). https://doi.org/10.1080/02670836.2020.1763555
Švecová, I., Tillová, E., Kuchariková, L., & Knap, V. Possibilities of predicting undesirable iron intermetallic phases in secondary Al-alloys. Transportation Research Procedia, 55, 797-804 (2021). https://doi.org/10.3390/electronicmat3010001
Fracchia, E., Lombardo, S., & Rosso, M. Case study of a functionally graded aluminum part. Applied Sciences, 8(7), 1113(2018). https://doi.org/ 10.3390/app8071113
Fracchia, E., Gobber, F. S., Rosso, M., Actis Grande, M., Bidulská, J., & Bidulský, R. Junction characterization in a functionally graded aluminum part. Materials, 12(21), 3475 (2019). https://doi.org/10.3390/ma12213475
G Gao, T., Li, Z., Zhang, Y., Qin, J., & Liu, X. Phase evolution of β-Al 5 FeSi during recycling of Al–Si–Fe alloys by Mg melt. International Journal of Metalcasting, 13, 473-478 (2019). https://doi.org/10.1007/s40962-018-0279-3
Wang, J., Liu, S., Bai, X., Zhou, X., & Han, X. Oxidation behavior of Fe–Al–Cr alloy at high temperature: Experiment and a first principle study. Vacuum, 173, 109144 (2020). https://doi.org/10.1016/j.vacuum.2019.109144
Galano, M., Audebert, F., Escorial, A. G., Stone, I. C., & Cantor, B. Nanoquasicrystalline Al–Fe–Cr-based alloys. Part II. Mechanical properties. Acta materialia, 57(17), 5120-5130 (2009). https://doi.org/10.1016/j.actamat.2009.07.009
Que, Z., Wang, Y., Mendis, C. L., Fang, C., Xia, J., Zhou, X., & Fan, Z. Understanding Fe-containing intermetallic compounds in Al alloys: an overview of recent advances from the LiME research hub. Metals, 12(10), 1677 (2022). https://doi.org/10.3390/met12101677
Gao, T., Li, Z., Zhang, Y., Qin, J., & Liu, X. Phase evolution of β-Al 5 FeSi during recycling of Al–Si–Fe alloys by Mg melt. International Journal of Metalcasting, 13, 473-478 (2019). https://doi.org/10.1007/s40962-018-0279-3
Sheshukov, O. Y., & Kataev, V. V. Influence of Titanium and Zirconium on the Structure and Heat-Resistance of Low-Carbon Iron–Aluminum Alloys. Steel in Translation, 51, 621-626 (2021). https://doi.org/10.1179/174328407X168766
Chen, H. Z., Li, B. R., Wen, B., Ye, Q., & Zhang, N. Q. Corrosion behaviours of iron-chromium-aluminium steel near the melting point of various eutectic salts. Solar Energy Materials and Solar Cells, 210, 110510 (2020). https://doi.org/10.1016/j.solmat.2020.110510
Behrens, B. A., Brunotte, K., Petersen, T., & Relge, R. Investigation on the Microstructure of ECAP-Processed Iron-Aluminium Alloys. Materials, 14(1), 219 (2021). jhttps://doi.org/10.3390/ma14010219
Siekaniec, D., Kopyciński, D., Tyrała, E., Guzik, E., & Szczęsny, A. Optimisation of solidification structure and properties of hypoeutectic chromium cast iron. Materials, 15(18), 6243 (2022). https://doi.org/10.3390/ma15186243
Babilas, R., Bajorek, A., Spilka, M., Radoń, A., & Łoński, W. Structure and corrosion resistance of Al–Cu–Fe alloys. Progress in Natural Science: Materials International, 30(3), 393-401 (2020). https://doi.org/10.1016/j.pnsc.2020.06.002
Pérez-Prado, M. T., Martin, A., Shi, D. F., Milenkovic, S., & Cepeda-Jiménez, C. M. An Al-5Fe-6Cr alloy with outstanding high temperature mechanical behavior by laser powder bed fusion. Additive Manufacturing, 55, 102828(2022). https://doi.org/ 10.1016/j.addma.2022.102828
Koller, C. M., Kirnbauer, A., Dalbauer, V., Kolozsvári, S., Ramm, J., & Mayrhofer, P. H. On the oxidation behavior of cathodic arc evaporated Al-Cr-Fe and Al-Cr-Fe-O coatings. I. Journal of Vacuum Science & Technology A, 37(4) (2019). https://doi.org/ 10.1116/1.5099123
Sourani, F., Enayati, M. H., & Ngan, A. H. W. On the in situ synthesis of (Fe, Cr) Al and (Fe, Cr) Al–Al2O3 nanostructured materials. Materials Research Express, 6(8), 0850c9(2019). https://doi.org/ 10.1088/2053-1591/ab24f5
Skorodzievskii, V. S., Ustinov, A. I., Polishchuk, S. S., Demchenkov, S. A., & Telychko, V. O. Dissipative properties of Al-(Fe, Cr) vacuum coatings with different composite structures. Surface and Coatings Technology, 367, 179-186(2019). https://doi.org/ 10.1016/j.surfcoat.2019.03.074
Muneer, B. A. I. G., Ammar, H. R., Seikh, A. H., Mohammed, J. A., Fahad, A. M., & Alaboodi, A. Thermal stability of nanocrystalline Al− 10Fe− 5Cr bulk alloy. Transactions of Nonferrous Metals Society of China, 29(2), 242-252(2019). https://doi.org/ 10.1016/S1003-6326(16)64128-6
Shockner, R., Edry, I., Pinkas, M., & Meshi, L. Systematic study of the effect of Cr on the microstructure, phase content and hardness of the AlCrxFeCoNi alloys. Journal of Alloys and Compounds, 940, 168897(2023). https://doi.org/ 10.1116/1.5099123
Shi, H., Jianu, A., Fetzer, R., Szabo, D. V., Schlabach, S., Weisenburger, A., & Mueller, G. Compatibility and microstructure evolution of Al-Cr-Fe-Ni high entropy model alloys exposed to oxygen-containing molten lead. Corrosion Science, 189, 109593(2021). https://doi.org/10.1016/j.corsci.2021.109593
Abid Ali,A Raheem Kadhim, Al-Ethari,H and Hasan,A Abbas. (2025). Mechanical properties of functionally graded Al-Cr-Fe alloy fabricated by sequential casting with influence of vibration. Al-Qadisiyah Journal for Engineering Sciences, 18(2), 126-130. doi: 10.30772/qjes.2024.151081.1280
MLA
Abid Ali,A Raheem Kadhim, , Al-Ethari,H , and Hasan,A Abbas. "Mechanical properties of functionally graded Al-Cr-Fe alloy fabricated by sequential casting with influence of vibration", Al-Qadisiyah Journal for Engineering Sciences, 18, 2, 2025, 126-130. doi: 10.30772/qjes.2024.151081.1280
HARVARD
Abid Ali A Raheem Kadhim, Al-Ethari H, Hasan A Abbas. (2025). 'Mechanical properties of functionally graded Al-Cr-Fe alloy fabricated by sequential casting with influence of vibration', Al-Qadisiyah Journal for Engineering Sciences, 18(2), pp. 126-130. doi: 10.30772/qjes.2024.151081.1280
CHICAGO
A Raheem Kadhim Abid Ali, H Al-Ethari and A Abbas Hasan, "Mechanical properties of functionally graded Al-Cr-Fe alloy fabricated by sequential casting with influence of vibration," Al-Qadisiyah Journal for Engineering Sciences, 18 2 (2025): 126-130, doi: 10.30772/qjes.2024.151081.1280
VANCOUVER
Abid Ali A Raheem Kadhim, Al-Ethari H, Hasan A Abbas. Mechanical properties of functionally graded Al-Cr-Fe alloy fabricated by sequential casting with influence of vibration. QJES. 2025;18(2):126-130. doi: 10.30772/qjes.2024.151081.1280